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Hosts Lyon have won the title each year since 2016 and the fixture had been moved after they had registered numerous cases of Covid-19 in their squad.
The holders had won the first leg 1-0 in the French capital but the Parisians bounced back at the OL Stadium to secure a last four meeting with Barcelona.
USA forward Catarina Macario scored early before a PSG comeback.
France midfielder Grace Geyoro equalised after 25 minutes with a rifling shot into the top corner before Wendie Renard's second-half own goal which won the tie for PSG.
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Forward Kadidiatou Diani broke down the right and Lyon captain Renard guided her dangerous cross into her own net on the hour mark.
In the other semi-final Bayern Munich face Chelsea with the first legs on April 24-25 and the return legs on May 1-2.
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